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11.
Dissolution rates of natural illite (Illite du Puy) were measured from Si release rates during closed system experiments at pH ranging from 1.4 to 12.4 and temperatures ranging from 5 to 50°C. Experiments performed at 4<pH<11 exhibited reactive fluid Si/Al concentration ratios that were inconsistent with stoichiometric illite dissolution likely due to secondary phase precipitation. In contrast, after an initial preferential release of aluminum relative to silicon, the reactive fluid Si/Al concentration ratio evolution was consistent with stoichiometric illite dissolution for all experiments conducted at 4>pH>11. Si release rate decreased with time during all experiments; for those experiments performed at 4>pH>11 this observation can be attributed to either 1) changing reactive surface area; 2) the effect of initial fine particle dissolution; or 3) a negative order of the illite dissolution reaction with respect to aqueous Al and/or Si. Measured dissolution rates exhibited a typical variation with pH; rates decrease with increasing pH at acid conditions, minimize at near to neutral pH and increase with increasing pH at basic conditions. An empirical expression describing rates obtained in the present study is given by
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12.
We question the correlation between vertical velocity (w) on the one hand and the occurrence of convective plumes in lidar reflectivity (i.e. range corrected backscatter signal Pz 2) and depolarization ratio (Δ) on the other hand in the convective boundary layer (CBL). Thermal vertical motion is directly investigated using vertical velocities measured by a ground-based Doppler lidar operating at 2 μm. This lidar provides also simultaneous measurements of lidar reflectivity. In addition, a second lidar 200 m away provides reflectivities at 0.53 and 1 μm and depolarization ratio at 0.53 μm. The time series from the two lidars are analyzed in terms of linear correlation coefficient (ρ). The main result is that the plume-like structures provided by lidar reflectivity within the CBL as well as the CBL height are not a clear signature of updrafts. It is shown that the lidar reflectivity within the CBL is frequently anti-correlated (ρ (w, Pz 2 )) with the vertical velocity. On the contrary, the correlation coefficient between the depolarization ratio and the vertical velocity ρ (w, Δ ) is always positive, showing that the depolarization ratio is a fair tracer of updrafts. The importance of relative humidity on the correlation coefficient is discussed. An erratum to this article can be found at  相似文献   
13.
We apply a novel adaptive mesh refinement (AMR) code, AMRVAC (Adaptive Mesh Refinement version of the Versatile Advection Code), to numerically investigate the various evolutionary phases in the interaction of a relativistic shell with its surrounding cold interstellar medium (ISM). We do this for both 1D isotropic and full 2D jet-like fireball models. This is relevant for gamma-ray bursts (GRBs), and we demonstrate that, thanks to the AMR strategy, we resolve the internal structure of the shocked shell–ISM matter, which will leave its imprint on the GRB afterglow. We determine the deceleration from an initial Lorentz factor  γ= 100  up to the almost Newtonian     phase of the flow. We present axisymmetric 2D shell evolutions, with the 2D extent characterized by their initial opening angle. In such jet-like GRB models, we discuss the differences with the 1D isotropic GRB equivalents. These are mainly due to thermally induced sideways expansions of both the shocked shell and shocked ISM regions. We found that the propagating 2D ultrarelativistic shell does not accrete all the surrounding medium located within its initial opening angle. Part of this ISM matter gets pushed away laterally and forms a wide bow-shock configuration with swirling flow patterns trailing the thin shell. The resulting shell deceleration is quite different from that found in isotropic GRB models. As long as the lateral shell expansion is merely due to ballistic spreading of the shell, isotropic and 2D models agree perfectly. As thermally induced expansions eventually lead to significantly higher lateral speeds, the 2D shell interacts with comparably more ISM matter and decelerates earlier than its isotropic counterpart.  相似文献   
14.
Laguna Chichój (Lake Chichój) is the only deep permanent lake in the central highlands of Guatemala. The lake is located in the boundary zone between the North American and Caribbean plates. The lake has been struck by devastating earthquakes and tropical cyclones in historical times. We investigated the imprint of twentieth century extreme events on the sedimentary record of this tropical lake using a bathymetric survey of the lake, coring the lake floor, and providing a chronology of sediment accumulation. The lake occupies a series of circular depressions likely formed by the rapid dissolution of a buried body of gypsum. 210Pb and 137Cs inventories and varve counting indicate high rates of sedimentation (1–2 cm year?1). The annually layered sediment is interrupted by turbidites of two types: a darker-colored turbidite, enriched in lake-derived biogenic constituents, and interpreted as a seismite, and a lighter-colored type, enriched in catchment-derived constituents, interpreted as a flood layer. Comparison of our 137Cs-determined layer ages with a catalog of twentieth century earthquakes shows that an earthquake on the Motagua fault in 1976 generated a conspicuous darker-colored turbidite and slumped deposits in separate parts of the lake. The entire earthquake inventory further reveals that mass movements in the lake are triggered at Modified Mercalli Intensities higher than V. Tropical cyclonic depressions known to have affected the lake area had limited effect on the lake, including Hurricane Mitch in 1998. One storm however produced a significantly thicker flood layer in the 1940s. This storm is reportedly the only event to have generated widespread slope failures in the lake catchment. It is thus inferred that abundant landsliding provided large amounts of concentrated sediment to the lake, through hyperpycnal flows.  相似文献   
15.
The discovery of solar-like oscillations in the giant star ξ Hya (G7 III) was reported by Frandsen et al. (2002). Their frequency analysis was very limited due to alias problems in the data set (caused by single-site observations). The extent to which the aliasing affected their analysis was unclear due to the unknown damping time of the stellar oscillation modes. In this paper we describe a simulator created to generate time series of stochastically excited oscillations, which takes as input an arbitrary window function and includes both white and non-white noise. We also outline a new method to compare a large number of simulated time series with an observed time series to determine the damping time, amplitude, and limited information on the degree of the stochastically excited modes. For ξ Hya we find the most likely amplitude to be ∼ 2 m s−1, in good agreement with theory (Houdek and Gough, 2002), and the most likely damping time to be ∼ 2 days, which is much shorter than the theoretical value of 15–20 days calculated by Houdek and Gough (2002).  相似文献   
16.
17.
The structure and vibrational spectrum of boehmite have been investigated at the quantum-mechanical level with the CRYSTAL code, using a Gaussian-type basis set and the B3LYP Hamiltonian. Three space groups are considered in this study: Cmcm, Cmc21, P21/c. Cmcm turns out to correspond to a transition state, whereas Cmc21 and P21/c are minimum energy structures. The difference among them is the position of H atoms only, the Al-O frame being essentially the same. Harmonic frequencies at the Γ point have been computed. The comparison between calculated and experimental frequencies shows a good agreement for the Al-O part of the spectrum (under 790 cm−1). For the Al-OH bending modes (800–1,300 cm−1) an absolute differences of 50–100 cm−1 is observed; for the OH stretching modes (3,200–3,500 cm−1) it increases to 120–200 cm−1: anharmonicity is large because OH groups are involved in strong hydrogen bonds.  相似文献   
18.
Mitigating and adapting to global changes requires a better understanding of the response of the Biosphere to these environmental variations. Human disturbances and their effects act in the long term (decades to centuries) and consequently, a similar time frame is needed to fully understand the hydrological and biogeochemical functioning of a natural system. To this end, the ‘Centre National de la Recherche Scientifique’ (CNRS) promotes and certifies long-term monitoring tools called national observation services or ‘Service National d'Observation’ (SNO) in a large range of hydrological and biogeochemical systems (e.g., cryosphere, catchments, aquifers). The SNO investigating peatlands, the SNO ‘Tourbières’, was certified in 2011 ( https://www.sno-tourbieres.cnrs.fr/ ). Peatlands are mostly found in the high latitudes of the northern hemisphere and French peatlands are located in the southern part of this area. Thus, they are located in environmental conditions that will occur in northern peatlands in coming decades or centuries and can be considered as sentinels. The SNO Tourbières is composed of four peatlands: La Guette (lowland central France), Landemarais (lowland oceanic western France), Frasne (upland continental eastern France) and Bernadouze (upland southern France). Thirty target variables are monitored to study the hydrological and biogeochemical functioning of the sites. They are grouped into four datasets: hydrology, fluvial export of organic matter, greenhouse gas fluxes and meteorology/soil physics. The data from all sites follow a common processing chain from the sensors to the public repository. The raw data are stored on an FTP server. After operator or automatic processing, data are stored in a database, from which a web application extracts the data to make them available ( https://data-snot.cnrs.fr/data-access/ ). Each year at least, an archive of each dataset is stored in Zenodo, with a digital object identifier (DOI) attribution ( https://zenodo.org/communities/sno_tourbieres_data/ ).  相似文献   
19.
Both increasing aridity and population growth strongly stress freshwater resources in semi-arid areas such as Jordan. The country’s second largest governorate, Irbid, with over 1 million inhabitants, is already suffering from an annual water deficit of 25 million cubic meters (MCM). The population is expected to double within the next 20 years. Even without the large number of refugees from Syria, the deficit will likely increase to more then 50 MCM per year by 2035 The Governorate’s exclusive resource is groundwater, abstracted by the extensive Al Arab and Kufr Asad well fields. This study presents the first three-dimensional transient regional groundwater flow model of the entire Wadi al Arab to answer important questions regarding the dynamic quality and availability of water within the catchment. Emphasis is given to the calculation and validation of the dynamic groundwater recharge, derived from a multi-proxy approach, including (1) a hydrological model covering a 30-years dataset, (2) groundwater level measurements and (3) information about springs. The model enables evaluation of the impact of abstraction on the flow regime and the groundwater budget of the resource. Sensitivity analyses of controlling parameters indicate that intense abstraction in the southern part of the Wadi al Arab system can result in critical water-level drops of 10 m at a distance of 16 km from the production wells. Moreover, modelling results suggest that observed head fluctuations are strongly controlled by anthropogenic abstraction rather than variable recharge rates due to climate changes.  相似文献   
20.
The barrier layer (BL) — a salinity stratification embedded in the upper warm layer — is a common feature of the tropical oceans. In the northern Indian Ocean, it has the potential to significantly alter the air–sea interactions. In the present paper, we investigate the spatio-temporal structure of BL in the Arabian Sea during summer monsoon. This season is indeed a key component of the Asian climate. Based on a comprehensive dataset of Conductivity–Temperature–Depth (CTD) and Argo in situ hydrographic profiles, we find that a BL exists in the central Arabian Sea during summer. However, it is highly heterogeneous in space, and intermittent, with scales of about ~100 km or less and a couple of weeks. The BL patterns appear to be closely associated to the salinity front separating two water masses (Arabian Sea High Salinity Water in the Northern and Eastern part of the basin, fresher Bay of Bengal Water to the south and to the west). An ocean general circulation model is used to infer the formation mechanism of the BL. It appears that thick (more than 40 m) BL patterns are formed at the salinity front by subduction of the saltier water mass under the fresher one in an area of relatively uniform temperature. Those thick BL events, with variable position and timing, result in a broader envelope of thinner BL in climatological conditions. However, the individual patterns of BL are probably too much short-lived to significantly affect the monsoonal air–sea interactions.  相似文献   
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